CN+, v = 1 – 0
Nitrilomethylium, v = 1 – 0
Species tag 026509
Version1*
Date of EntryOct. 2023
ContributorS. Thorwirth
H. S. P. Müller

An isotopic independent fit was published in
(1) J. L. Doménech, O. Asvany, C. R. Markus, S. Schlemmer, and S. Thorwirth, 2020, J. Mol. Spectrosc. 374, Art. No. 111375.
Some higher order parameters were evaluated in comparison to the neutral CN molecule by
(2) H. S. P. Müller, 2023, unpublished.
Rotational transition frequencies were reported by
(3) S. Thorwirth, P. Schreier, T. Salomon, S. Schlemmer, and O. Asvany, 2019, Astrophys. J. Lett. 882, Art. No. L6.
Rovibrational transition frequencies were taken from (1).
Various Combination differences were derived in (1) from
(4) A. Douglas and P. M. Routly, 1954, Astrophys. J. 119, 303.
Transition frequencies with calculated uncertainties exceeding 30 MHz or 0.001 cm–1 should be viewed with caution.
The partition function takes into account the 14N spin multiplicity to be consistent with the pure rotational entry 026508.
The transition dipole moment was taken from a quantum chemical calculation in
(5) K. A. Peterson, 1995, J. Chem. Phys. 102, 262.

Lines Listed61
Frequency / GHz< 62896
Max. J31
log STR0-100.0
log STR1-8.0
Isotope Corr. 
Egy / cm–10.0
 µa / D0.0613
 µb / D 
 µc / D 
 A / MHz 
 B / MHz56556.899
 C / MHz 
 Q(1000.0)332.8598
 Q(500.0)332.8598
 Q(300.0)332.8598
 Q(225.0)249.8308
 Q(150.0)166.8564
 Q(75.00)83.9175
 Q(37.50)42.4657
 Q(18.75)21.7543
 Q(9.375)11.4234
 Q(5.000)6.6481
 Q(2.725)4.2658
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder