13C18O
Carbon Monoxide, doubly substituted isotopolog with 13C and 18O
Species tag 031502
Version2*
Date of EntryApr. 2025
ContributorH. S. P. Müller

The initial experimental measurements were taken from
(1) G. Klapper, F. Lewen, S. P. Belov, and G. Winnewisser, 2000, Z. Naturforsch. A 55, 441
;
covering J" = 0 – 8. Transitions up to J" = 5 display resolved 13C hyperfine structure (HFS) splitting. With respect to the first entry from July 2000, more accurate low-J data (up to 2 – 1 near 209 GHz) were included which come from
(2) C. Puzzarini, L. Dore, and G. Cazzoli, 2003, J. Mol. Spectrosc., 217, 19
,
replacing the corresponding data from (1). In addition, J" = 23 and 24 frequencies were added from
(3) J. C. Pearson, B. J. Drouin, A. Maestrini, I. Mehdi, J. Ward, R. H. Lin, S. Yu, J. J. Gill, B. Thomas, C. Lee, G. Chattopadhyay, E. Schlecht, F. W. Maiwald, P. F. Goldsmith, and P. Siegel, 2011, Rev. Sci. Instrum., 82, Art. No. 093105.
The uncertainty of the stronger HFS component of the J = 6 – 5 transition was increase from 2 to 5 kHz. The transition frequencies should be quite reliable up to about 3 THz. Please note that the partition function still only refers to the ground vibrational state.
The HFS splitting caused by the 13C nucleus may be relevant in quiescent sources for low values of J. Therefore, a separate hyperfine calculation is provided for J" up to 2. NOTE: The partition function does take into account the spin multiplicity of the 13C nucleus !
The dipole moment and its centrifugal distortion corrections were taken from
(4) D. Goorvitch 1994, Astrophys. J. Suppl. 95, 535.

Lines Listed41
Frequency / GHz< 4252
Max. J41
log STR0-9.0
log STR1-9.0
Isotope Corr. 
Egy / (cm–1)0.0
 µa / D0.11067
 µb / D 
 µc / D 
 A / MHz 
 B / MHz52356.001
 C / MHz 
 Q(500.0)399.1053
 Q(300.0)239.6201
 Q(225.0)179.8514
 Q(150.0)120.1038
 Q(75.00)60.3783
 Q(37.50)30.5267
 Q(18.75)15.6099
 Q(9.375)8.1666
 Q(5.000)4.7209
 Q(2.725)2.9887
detected in ISM/CSMyes


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder