The experimental data was reported by
(1) C. A. Gottlieb, T. C. Killian, P. Thaddeus, P. Botschwina, J. Flügge, and M. Oswald,
1993, J. Chem. Phys. 98, 4478; and from
(2) M. C. Mc. Carthy and P. Thaddeus,
2002, J. Mol. Spectrosc. 211, 235.
The predictions, in particular at higher J or Ka,
should be viewed with some caution.
13C nuclear spin-rotation splitting may be
resolvable at low values of J. Respective data are from (2).
The dipole moment is from a quantum chemical calculation.
At low temperatures, it may be necessary to discern between
ortho-l-C3H2
and para-l-C3H2.
The ortho states are described by Ka odd,
the para states by Ka even.
The nuclear spin-weights are 3 and 1 for ortho-l-C3H2
and para-l-C3H2, respectively.
The JKaKc = 111
is the lowest ortho state. It is approximately 9.966 cm1 above ground.
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