The first entry from June 2006 was reevaluated considerably
because of additional millimeter and submillimeter data.
The initial transition frequencies were taken from
(1) M. Rodler, R. D. Brown, P. D. Godfrey, and L. M. Tack,
1984, Chem. Phys. Lett. 110, 447;
and from
(2) M. Rodler, R. D. Brown, P. D. Godfrey, and B. Kleibömer,
1986, J. Mol. Spectrosc. 118, 267.
New millimeter and submillimeter data were taken from
(3) C. Degli Esposti, L. Dore, and L. Bizzocchi,
2014, Astron. Astrophys. 565, Art. No A66.
Two of the three Ka = 2 – 1 rotational
transitions in (1) and (2) turned out to be misassigned,
causing substantial changes in part. The weak a-type
transitions were truncated after Ka = 7
because of the onset of a perturbation that is only
described moderately well.
NOTE: The present entry
provides 14N hyperfine splitting and the very
small tunneling splitting throughout because the molecule is
more likely associated with cold sources rather than warm ones.
The calculations are sufficiently accurate for observations
of cold sources and should also be accurate enough for
observation of warmer sources. Transition frequencies
with calculated uncertainties exceeding 0.1 MHz
should be viewed with caution.
The dipole moment was reported in (1).
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