Cyanic acid is a quasi-linear molecule close
to the non-linear limit.
The lines were taken from
(1) S. Brünken, C. A. Gottlieb, M. C. McCarthy,
and P. Thaddeus,
2009, Astrophys. J. 697, 880.
Predictions with uncertainties exceeding 0.5 MHz
should be viewed with caution. Predictions of
transitions with Ka = 3
and 4 should be viewed with some caution, all
higher Ka transitions with
great caution throughout.
14N hyperfine splitting may be resolved
for low values of J. Therefore, a
separate hyperfine calculation is provided for
J' ≤ 8 and Ka ≤ 1.
The Ka = 1 hfs splitting should be viewed
with caution as the corresponding parameter is from an ab initio
calculation.
NOTE: The partition function
does not take into account the spin multiplicity
gI = 3 of the 14N
nucleus !
The ab initio dipole moment was mentioned in (1).
The molecule has also a fairly large b-dipole
moment component. However, predictions would be completely
unreliable at present and have thus been omitted.
|