HOCN
Cyanic acid, hydrogen cyanate
Species tag 043510
Version1*
Date of EntryMay 2009
ContributorH. S. P. Müller

Cyanic acid is a quasi-linear molecule close to the non-linear limit. The lines were taken from
(1) S. Brünken, C. A. Gottlieb, M. C. McCarthy, and P. Thaddeus, 2009, Astrophys. J. 697, 880.
Predictions with uncertainties exceeding 0.5 MHz should be viewed with caution. Predictions of transitions with Ka = 3 and 4 should be viewed with some caution, all higher Ka transitions with great caution throughout.
14N hyperfine splitting may be resolved for low values of J. Therefore, a separate hyperfine calculation is provided for J' ≤ 8 and Ka ≤ 1. The Ka = 1 hfs splitting should be viewed with caution as the corresponding parameter is from an ab initio calculation. NOTE: The partition function does not take into account the spin multiplicity gI = 3 of the 14N nucleus !
The ab initio dipole moment was mentioned in (1). The molecule has also a fairly large b-dipole moment component. However, predictions would be completely unreliable at present and have thus been omitted.

Lines Listed1041
Frequency / GHz< 1500
Max. J72
log STR0-9.0
log STR1-5.0
Isotope Corr.-0.0
Egy / cm–10.0
 µa / D3.7
 µb / D 
 µc / D 
 A / MHz~681000
 B / MHz10577.01
 C / MHz10398.49
 Q(300.0)3217.0765
 Q(225.0)2087.4819
 Q(150.0)1135.3539
 Q(75.00)401.3740
 Q(37.50)142.1413
 Q(18.75)50.8159
 Q(9.375)20.1244
 Q(5.000)10.3038
 Q(2.725)5.7601
detected in ISM/CSMyes


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder