HNSi
Iminosilylene
Species tag 043516
Version1*
Date of EntryApr. 2014
ContributorH. S. P. Müller

The lines were reported in
(1) M. Bogey, C. Demuynck, J.-L. Destombes, and A. Walters, 1991, Astron. Astrophys. 244, L47.
The reported uncertainties were rather very conservative. Evidently, very much smaller uncertainties were assumed implicitely. The uncertainties used here are closer to the implicitely assumed ones, but they may still be a bit conservative.
The sextic distortion parameter H was estimated by comparison with the value of the isoelectronic HCP Molecule.
Should iminosilylene exist in circumstellar envelopes of late-type stars, then probably in the outer, cooler regions. Therefore, the predictions should be sufficient for astronomical observations. They should be reliable at least up to 1 THz.
The dipole moment is from an ab initio calculation by
(2) H. S. P. Müller and D. E. Woon, 2013, J. Phys. Chem. A 117, 13868.

Lines Listed45
Frequency / GHz< 1705
Max. J45
log STR0-6.0
log STR1-5.0
Isotope Corr.-0.0415
Egy / (cm–1)0.0
 µa / D0.250
 µb / D 
 µc / D 
 A 
 B19018.80
 C 
 Q(300.0)329.2416
 Q(225.0)246.9706
 Q(150.0)164.7290
 Q(75.00)82.5171
 Q(37.50)41.4228
 Q(18.75)20.8796
 Q(9.375)10.6112
 Q(5.000)5.8239
 Q(2.725)3.3427
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder