HSiO
Oxosilyl, silaformyl, X 2A'
Species tag 045514
Version1*
Date of EntryDec. 2012
ContributorH. S. P. Müller

The experimental lines are from
(1) M. Izuha, S. Yamamoto, and S. Saito, 1997, J. Mol. Struct. 413–414, 527.
The present fit employs Watson's S-reduction. With the inclusion of h3 and d2S, the standard deviation drops to 16.5 kHz from 24 kHz reported in (1).
The b-type transitions can not be predicted with confidence, and they are very weak. Therefore, their prediction was omitted. Predictions with calculated uncertainties larger than 0.5 MHz should be viewed with caution. The predictions should be sufficient for astronomical observations toward higher frequencies, whereas some caution is advised at lower frequencies because it is not clear if the hyperfine parameters are known accurately enough.
The dipole moment is derived from an ab initio calculation from
(2) J. Koput, 2002, J. Phys. Chem. A 106, 12067.

Lines Listed2254
Frequency / GHz< 1620
Max. J43
log STR0-6.0
log STR1-4.0
Isotope Corr.-0.0363
Egy / (cm–1)0.0
 µa / D3.386
 µb / D(0.039)
 µc / D 
 A / MHz312108.
 B / MHz19884.44
 C / MHz18607.98
 Q(300.0)10412.2716
 Q(225.0)6749.9798
 Q(150.0)3668.3768
 Q(75.00)1296.5520
 Q(37.50)459.6302
 Q(18.75)163.6526
 Q(9.375)58.9800
 Q(5.000)25.2519
 Q(2.725)13.2588
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder