DOCO+
Oxyhydroxymethylium, deuterated isotopolog
Species tag 046525
Version1*
Date of EntryJuly 2017
ContributorH. S. P. Müller

The entry is based on a recent report by
(1) L. Bizzocchi, V. Lattanzi, J. Laas, S. Spezzano, B. M. Giuliano, D. Prudenzano, C. Endres, O. Sipilä, and P. Caselli, 2017, Astron. Astrophys. 602, Art. No. A34.
As in that study, additional data were taken from
(2) M. Bogey, C. Demuynck, J.-L. Destombes, and A. Krupnov, 1988, J. Mol. Struct. 190, 465.
The ground state of DOCO+ is perturbed by the excited v5 = 1 state, albeit to a lesser extend the HOCO+. Since the molecule has been detected thus far in cold environments only, transition frequencies with Ka = 4 were omitted from the fit, and the predictions were limited to Ka ≤ 2.
Predictions with uncertainties larger than 0.2 MHz or b-type transitions with Ka = 2 should be viewed with caution.
The dipole moment was assumed to agree with that of HOCO+, see e045522.cat. Note that the values of the two components have essentially been interchanged with respect to earlier calculations.

Lines Listed946
Frequency / GHz< 2752
Max. J74
log STR0-6.0
log STR1-5.0
Isotope Corr.-3.815
Egy / cm–10.0
 µa / D2.7
 µb / D1.8
 µc / D 
 A / MHz432956.4
 B / MHz10163.993
 C / MHz9908.686
 Q(300.0)4227.1795
 Q(225.0)2741.5300
 Q(150.0)1490.2206
 Q(75.00)526.4741
 Q(37.50)186.3580
 Q(18.75)66.1552
 Q(9.375)24.1278
 Q(5.000)11.0571
 Q(2.725)6.0088
detected in ISM/CSMyes


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder