HS13C
Thiohydroxymethylidyne, X 2A', 13C isotopolog
Species tag 046530
Version1*
Date of EntryNov. 2022
ContributorH. S. P. Müller

The laboratory transition frequencies were reported by
(1) H. Habara and S. Yamamoto, 2003, J. Mol. Spectrosc. 219, 30.
One line with large residual was omitted from the fit. The present parameter set differs slightly from the one in (1). The calculated spectrum should be sufficient for all observational purposes. Caution is advised for frequencies with calculated uncertainties exceeding 0.1 MHz. Some caution is also suggested for transitions with relatively large HFS splitting as the parameters of H were taken from the parent species.
The dipole moment was assumed to agree with that of the main species, which should be sufficiently close. Its total dipole moment is from a quantum-chemical calculation by
(2) C. Ochsenfeld, R. I. Kaiser, Y. T. Lee, and M. Head-Gordon, 1999, J. Chem. Phys. 110, 9982;
the a and b components were derived in
(3) H. Habara and S. Yamamoto, 2000, J. Chem. Phys. 112, 10905
from relative intensity measurements. The uncertainties are probably several percent. We note that no b-type transitions were calculated as none were observed in the laboratory, such that there positions are too uncertain.

Lines Listed1797
Frequency / GHz< 720
Max. J19
log STR0-6.5
log STR1-4.3
Isotope Corr. 
Egy / cm–10.0
 µa / D2.45
 µb / D(0.95)
 µc / D 
 A / MHz294898.
 B / MHz19853.84
 C / MHz18536.86
 Q(300.0)21369.4946
 Q(225.0)13871.7530
 Q(150.0)7548.8058
 Q(75.00)2671.5997
 Q(37.50)947.7535
 Q(18.75)337.5967
 Q(9.375)121.5626
 Q(5.000)51.5070
 Q(2.725)26.7108
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder