The millimeter spectrum was reported in
(1) A. Guarnieri, R. Hinze, M. Krüger, H. Zerbe-Foese,
D. Lentz, and D. Preugschat,
1992, J. Mol. Spectrosc. 156, 39.
The ground state fundamental rotational transition with
14N hyperfine splitting was published in
(2) M. Krüger, W. Stahl, and H. Dreizler,
1993, J. Mol. Spectrosc. 158, 298.
The 14N nuclear spin-rotation parameter was
kept fixed to the value from a quantum-chemical calculation
by
(3) H. S. P. Müller, 2020, unpublished.
One line of (1) with large residual was omitted.
The sextic distortion parameter H was not used in the fit;
its omission may affect transition frequencies above about
500 GHz. The calculation may be accurate enough throughout.
14N hyperfine splitting matters in some
astronomical observations. Therefore, a
separate hyperfine calculation is provided for
J' ≤ 12 below 120 GHz.
NOTE: The partition function
does take into account the spin multiplicity
of the 14N nucleus !
The experimental dipole moment was published
by
(4) M. Krüger, H. Dreizler, D. Preugschat, and D. Lentz,
1991, Angew. Chem. 103, 1674.
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