The experimental data were taken from
(1) M. Winnewisser, B. P. Winnewisser, and C. Wentrup,
1984, J. Mol. Spectrosc., 105, 193.
Additional data with extensive 14N
hyperfine splitting were obtained in the
context of
(2) W. H. Stolze, D. H. Sutter, and C. Wentrup,
1989, Z. Naturforsch., 44A, 291.
Data of two of the four rotational transitions
were used because for the other two the frequencies
were apparently less certain than the HFS splitting.
The HFS structure is sufficiently well contrained.
Also used in the fit were data from
(3) B. Bak and H. Svanholt,
1980, Chem. Phys. Lett., 75, 528.
Predictions are probably accurate enough for
astronomical observations. They should be viewed
with caution once the predicted uncertainties
exceed 0.5 MHz.
The 14N hyperfine splitting may be resolved
in astronomical observations. Therefore, a separate
hyperfine calculation is provided up to J" = 18,
Ka" = 6, and up to 260 GHz
along with appropriate
partition function values.
The a dipole moment component was determined
in
(4) B. Bak, O. J. Nielsen, and H. Svanholt,
1978, Chem. Phys. Lett., 59, 330;
the b component was estimated in (3).
|