KOH
Potassium hydroxide, 1Σ+
Species tag 056514
Version1*
Date of EntryAug. 2009
ContributorH. S. P. Müller

The observed transitions were taken from
(1) E. F. Pearson, B. P. Winnewisser, and M. B. Trueblood, 1976, Z. Naturforsch. 31a, 1259;

from
(2) P. Kuipers, T. Törring, and A. Dymanus, 1975, Z. Naturforsch. 30a, 1256;

from
(3) T. T. Raw, T. Yamamura, C. W. Gillies, 1987, J. Chem. Phys. 87, 3706;

and from
(4) Y. Kawashima, R. D. Suenram, and E. Hirota, 1996, J. Mol. Spectrosc. 175, 99.
The predictions should be reliable up to 350 GHz.
At low values of J, 39K hyperfine splitting is resolvable. Therefore, a separate prediction considering 39K hyperfine splitting with J" ≤ 4 is available. Note: The partition function does not include the spin-multiplicities of 39K ! Therefore, partition function values have to be multiplied by 4 when considering 39K hyperfine splitting !
The dipole moment was taken from
(5) J. Cederberg, D. Olson, D. Rioux, T. Dillemuth, B. Borovsky, J. Larson, S. Cheah, M. Carlson, and M. Stohler, 1996, J. Chem. Phys. 105, 3361.

Lines Listed61
Frequency / GHz< 1000
Max. J61
log STR0-4.0
log STR1-3.0
Isotope Corr.-0.0314
Egy / cm–10.0
 µa / D7.415
 µb / D 
 µc / D 
 A / MHz 
 B / MHz8208.69
 C / MHz 
 Q(300.0)763.5119
 Q(225.0)572.4127
 Q(150.0)381.5126
 Q(75.00)190.8178
 Q(37.50)95.5493
 Q(18.75)47.9357
 Q(9.375)24.1349
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder