NaSH
Sodium hydrosulfide, X 1A'
Species tag 056522
Version1*
Date of EntryJuly 2018
ContributorH. S. P. Müller

Experimental results were published by
(1) E. Kagi and K. Kawaguchi, 1997, Astrophys. J. 491, L129.
The 23Na hyperfine split a-type transition frequencies were also included in the fit. They were reported by
(2) M. P. Bucchino, P. M. Sheridan, J. P. Young, M. K. L. Binns, D. W. Ewing, and L. M. Ziurys, 2013, J. Chem. Phys. 139, Art. No. 214307.
The experimental transition frequencies from (1) were kindly provided by K. Kawaguchi.
23Na HFS splitting may be resolvable at low values of J and higher values of Ka, but these transitions are deemed to be too weak even if the molecule will have been observed in space. The entry may be sufficiently accurate for all observational purposes. Transitions with predicted uncertainties exceeding 0.2 MHz should be viewed with some caution.
The dipole moment was taken from an ab initio calculation mentioned in (1). Even though the molecule posseses a moderately large b-dipole moment component, no such transitions were calculated because their frequencies are too uncertain.

Lines Listed1432
Frequency / GHz< 1000
Max. J85
log STR0-5.0
log STR1-3.5
Isotope Corr.-0.0223
Egy / cm–10.0
 µa / D8.91
 µb / D(0.63)
 µc / D 
 A / MHz292833.
 B / MHz6065.019
 C / MHz5927.774
 Q(500.0)18549.8576
 Q(300.0)8589.2082
 Q(225.0)5571.4291
 Q(150.0)3028.9909
 Q(75.00)1070.0528
 Q(37.50)378.5290
 Q(18.75)134.1226
 Q(9.375)47.7844
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder