NCS
Thiocyanogen, X 2Πi
Species tag 058504
Version2*
Date of EntryMay 2007
ContributorH. S. P. Müller

The lines have been reported in
(1) T. Amano and T. Amano, 1991, J. Chem. Phys. 95, 2275, and in
(2) M. C. McCarthy, A. L. Cooksy, S. Mohamed, V. D. Gordon, and P. Thaddeus, 2003, Astrophys. J. Suppl. Ser. 144, 287.
With respect to th March 2003 entry, additional submillimeter transitions were used in the fit. These were reported in
(3) A. Maeda, H. Habara, and T. Amano, 2007, Mol. Phys. 105, 477.
The fit has been carried out using constants and quantum numbers of Hund's case (b). 14N hyperfine splitting was not resolved for N" ≥ 10. Therefore, the new default entry does not consider this splitting ! However, it has to be considered in the microwave and lower millimeter wave regions. Therefore, a separate calculation with 14N hyperfine splitting is provided up to 141 GHz. The partition function takes into account the spin multiplicity gI = 3 of the 14N nucleus !
The dipole moment is from an ab initio calculation by
(4) H. S. P. Müller, unpublished.

Lines Listed378
Frequency / GHz< 1200
Max. J98
log STR0-7.0
log STR1-5.0
Isotope Corr.-0.0289
Egy / (cm-1)0.0
 µa / D2.45
 µb / D 
 µc / D 
 A 
 B6106.62
 C 
 Q(300.0)7440.2292
 Q(225.0)5191.8248
 Q(150.0)3218.8790
 Q(75.00)1551.1745
 Q(37.50)779.6290
 Q(18.75)395.3786
 Q(9.375)203.3583
detected in ISM/CSMyes


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder