AlSH
Aluminum monohydrosulfide, X 1A'
Species tag 060520
Version1*
Date of EntryJuly 2018
ContributorH. S. P. Müller

The experimental data were taken from
(1) A. Janczyk and L. M. Ziurys, 2006, Astrophys. J. 639, L107.
The 27Al hyperfine split a-type J = 1 – 0 transition frequencies were also included in the fit. They were reported by
(2) M. Fukushima and M. C. L. Gerry, 2010, J. Mol. Spectrosc. 262, 11.
Omitting a small number of transition with large residuals from (1), these data fit to 20 kHz, including the lines with Ka = 5 and 6. The parameter set differs only in one additional parameter from the the combined set of (1) and (2).
27Al HFS splitting may be resolvable at low values of J and higher values of Ka, but these transitions are deemed to be too weak even if the molecule will have been observed in space. The entry may be sufficiently accurate for all observational purposes. Transitions with predicted uncertainties exceeding 0.2 MHz should be viewed with some caution.
The dipole moment was taken from an ab initio calculation by
(3) H. S. P. Müller, 2018, unpublished.
Even though the molecule posseses a moderately large b-dipole moment component, no such transitions were calculated because their frequencies are too uncertain.

Lines Listed1228
Frequency / GHz< 1000
Max. J75
log STR0-6.0
log STR1-5.0
Isotope Corr.-0.0223
Egy / cm–10.0
 µa / D1.19
 µb / D(0.53)
 µc / D 
 A / MHz287674.
 B / MHz6796.989
 C / MHz6626.413
 Q(500.0)16665.9032
 Q(300.0)7727.2973
 Q(225.0)5014.9112
 Q(150.0)2727.8588
 Q(75.00)964.2239
 Q(37.50)341.2282
 Q(18.75)120.9571
 Q(9.375)43.1093
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder