H2CC34S
Ethenthione, thioketene, 34S isotopolog
Species tag 060532
Version1*
Date of EntryMay 2022
ContributorH. S. P. Müller

The experimental lines are from
(1) B. Bak, O. J. Nielsen, H. Svanholt, A. Holm, N. H. Tourbro, A. Krantz, and J. Laureni, 1979, Acta Chem. Scand. A 33, 161.
Some higher order centrifugal distortion constants were estimated by
(2) H. S. P. Müller, 2022, unpublished.
Calculations of transition frequencies with Ka = 0 and 1 may be reliable into the 3 mm range. Transition frequencies with Ka larger than 1 should be viewed with increasing caution. The calculation were limited to Ka = 5.
At low temperatures, it may be necessary to discern between ortho-H2CC34S and para-H2CC34S. The ortho states are described by Ka odd, the para states by Ka even. The nuclear spin-weights are 3 and 1 for ortho-H2CC34S and para-H2CC34S, respectively. The JKaKc = 111 level is the lowest ortho level. It is 9.7357 cm–1 above ground.
The dipole moment of the main isotopolog was determined by
(3) M. Winnewisser and E. Schäfer, 1980, Z. Naturforsch. A 35, 483.

Lines Listed196
Frequency / GHz< 200
Max. J18
log STR0-11.0
log STR1-5.5
Isotope Corr. 
Egy / (cm–1)0.0
 µa / D1.01
 µb / D 
 µc / D 
 A / MHz286687
 B / MHz5531.58
 C / MHz5421.70
 Q(300.0)18948.8525
 Q(225.0)12301.8596
 Q(150.0)6693.8486
 Q(75.00)2366.6944
 Q(37.50)836.4880
 Q(18.75)286.4889
 Q(9.375)86.0554
 Q(5.000)26.7878
 Q(2.725)11.1208
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder