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The experimental lines without 33S hyperfine splitting
are from
(1) A. Dubrulle, J. Demaison, J. Burie, and D. Boucher,
1980, Z. Naturforsch. 35a, 471;
and from
(2) A. V. Burenin, A. N. Val'dov, E. N. Karyakin,
A. F. Krupnov, and S. M. Shapin,
1981, J. Mol. Spectrosc. 87, 312.
The 33S hyperfine split 2 – 1
transition was taken from
(3) I. Merke and H. Dreizler,
1987, Z. Naturforsch. 42a, 1043;
and the corresponding 1 – 0 transition from
(4) J. W. Bevan, A. C. Leogon, and C. A. Rego,
1992, J. Chem. Soc. Faraday Trans. 88, 3110.
Predictions beyond J = 60 should be
viewed with some caution.
The 33S hyperfine splitting may be resolved for
lower J transitions. Therefore, a separate
hyperfine calculation up to J" = 15 is provided.
The 33S spin multiplicity of 4 was considered
in the calculation of the partition function !
The dipole moment was estimated from
(5) K. Tanaka, T. Tanaka, and I. Suzuki
1985, J. Chem. Phys. 82, 2835.
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