The experimental lines are from
(1) F. X. Brown, S. Yamamoto, and S. Saito,
1997, J. Mol. Struct. 413414, 537.
Most of the lines weighted out in (1) were also weighted
out here. Two lines fit quite well and were weighted in,
though one was given a larger uncertainty together with
the adjacent HFS component. One typograpohical error
was corected. The present fit employs Watson's S-reduction.
Similar to (1), DK and HK
were kept fixed to values from HS2
summarized in
(2) M. Tanimoto, T. Klaus, H. S. P. Müller, and
G. Winnewisser,
2000, J. Mol. Spectrosc. 199, 73;
in addition, a value for HKS
was guessed. The hyperfine parameter Tbb
was locked to Taa, a constraint
reasonable with the present data set, but unlikely to
hold strictly.
The b-type transitions can not be predicted
with confidence, and they are rather weak. Therefore,
their prediction was omitted. Predictions with
calculated uncertainties larger than 0.5 MHz
should be viewed with caution, in particular at
low frequencies at which the hyperfine splitting
is less certain. These limitations are deemed to be
more important for astronomical observations than
the increase in uncertainty at higher Ka
or higher frequencies.
The dipole moment is from an ab initio calculation
from
(3) D. E. Woon and E. Herbst,
2009, Astrophys. J. Suppl. Ser. 185, 273.
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