HSiS
Thiosilyl, thiosilaformyl, X 2A'
Species tag 061512
Version1*
Date of EntryDec. 2012
ContributorH. S. P. Müller

The experimental lines are from
(1) F. X. Brown, S. Yamamoto, and S. Saito, 1997, J. Mol. Struct. 413–414, 537.
Most of the lines weighted out in (1) were also weighted out here. Two lines fit quite well and were weighted in, though one was given a larger uncertainty together with the adjacent HFS component. One typograpohical error was corected. The present fit employs Watson's S-reduction. Similar to (1), DK and HK were kept fixed to values from HS2 summarized in
(2) M. Tanimoto, T. Klaus, H. S. P. Müller, and G. Winnewisser, 2000, J. Mol. Spectrosc. 199, 73;
in addition, a value for HKS was guessed. The hyperfine parameter Tbb was locked to Taa, a constraint reasonable with the present data set, but unlikely to hold strictly.
The b-type transitions can not be predicted with confidence, and they are rather weak. Therefore, their prediction was omitted. Predictions with calculated uncertainties larger than 0.5 MHz should be viewed with caution, in particular at low frequencies at which the hyperfine splitting is less certain. These limitations are deemed to be more important for astronomical observations than the increase in uncertainty at higher Ka or higher frequencies.
The dipole moment is from an ab initio calculation from
(3) D. E. Woon and E. Herbst, 2009, Astrophys. J. Suppl. Ser. 185, 273.

Lines Listed4333
Frequency / GHz< 1160
Max. J70
log STR0-7.3
log STR1-5.0
Isotope Corr.-0.0575
Egy / (cm–1)0.0
 µa / D2.044
 µb / D(0.249)
 µc / D 
 A / MHz305695.
 B / MHz8410.87
 C / MHz8168.03
 Q(300.0)24254.9468
 Q(225.0)15745.2975
 Q(150.0)8567.0355
 Q(75.00)3029.2385
 Q(37.50)1072.3412
 Q(18.75)380.2824
 Q(9.375)135.7974
 Q(5.000)56.9843
 Q(2.725)28.9084
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder