SiCl+, v = 0, 1
Chlorosilylidynium, X 1Σ+, v = 0, 1
Species tag 063513
Version1*
Date of EntrySep. 2023
ContributorH. S. P. Müller

Rotational data were taken from
(1) K. Takeda, S. Masuda, K. Harada, and K. Tanaka, 2016, Chem. Phys. Lett. 651, 168.
Transition frequencies with Cl hyperfine splitting were published by
(2) K. Tanaka, K. Harada, C. Cabezas, and Y. Endo, 2018, J. Mol. Spectrosc. 345, 39.
Rovibrational data were also included. These were taken from
(3) Y. Sumiyoshi, K. Tanaka, and T. Tanaka, 1993, Chem. Phys. Lett. 214, 17;
and from
(4) W. Y. Fan, Z. Liu, and P. B. Davies, 1998, J. Mol. Spectrosc. 191, 99.
The Dunham fit follows (4) with modifications related to (2). Hyperfine splitting was deemed to be unimportant for observational purposes. Transition frequencies should be reliable up to 300 GHz, possibly higher.
The dipole moment was taken from a quantum-chemical calculation in (2).
The partition function takes excited vibrational states into account.

Lines Listed58
Frequency / GHz< 500
Max. J29, 29
log STR0-7.0
log STR1-3.5
Isotope Corr. 
Egy / cm–10.0, 1040.48
 µa / D3.412
 µb / D 
 µc / D 
 A / MHz 
 B / MHz8582.04, 8537.65
 C / MHz 
 Q(2000.)4223.5107
 Q(1500.)2625.8237
 Q(1000.)1415.4856
 Q(500.0)575.8648
 Q(300.0)330.2426
 Q(225.0)246.3269
 Q(150.0)164.0836
 Q(75.00)82.1853
 Q(37.50)41.2556
 Q(18.75)20.7957
 Q(9.375)10.5692
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder