Al37Cl v = 0 – 10
Aluminum monochloride, 37Cl isotopolog, X 1Σ+, v = 0 – 10
Species tag 064519
Version1*
Date of EntryJuly 2019
ContributorH. S. P. Müller

Rotational transition frequencies were reported mostly by
(1) F. C. Wyse, and W. Gordy, 1972, J. Chem. Phys. 56, 2130.
Very accurate ground vibrational and ground rotational transition frequencies were published by
(2) K. D. Hensel, C. Styger, W. Jäger, A. J. Merer, and M. C. L. Gerry, 1993, J. Chem. Phys. 99, 3320.
Also used in the model were rovibrational transition frequencies from
(3) H. G. Hedderich, M. Dulick, and P. F. Bernath, 1993, J. Chem. Phys. 99, 8363.
The quality of the data from (3) differs very much. Unfortunately, no individual uncertainties were given. Therefore, lines with large residuals were omitted, and uncertainties were estimated for the remainder of the lines in each state and for each isotopolog. The present analysis follows largely the constrained one from that work.
The calculated transitions should be accurate enough for all observational purposes. Some caution may be advised for those at high v (above about 8) and higher J. Al or Cl hyperfine splitting may be resolvable at very low J, but these transitions are likely too weak to be observable.
The first 20 vibrational states were included in the calculation of partition function values.
The dipole moments from a quantum-chemical calculation were reported by
(4) M. Yousefi and P. F. Bernath, 2018, Astrophys. J. Suppl. Ser. 273, Art. No. 8.

Lines Listed1426
Frequency / GHz< 2000
Max. J149
log STR0-15.0
log STR1-14.0
Isotope Corr.-0.6157
Egy / cm–10.0, 471.99, 939.93, ...
 µa / D1.62967, 1.70061, ...
 µb / D 
 µc / D 
 A / MHz 
 B / MHz7117.512, ...
 C / MHz 
 Q(3000.)46009.8297
 Q(2500.)32514.5602
 Q(2000.)21294.6955
 Q(1500.)12468.5339
 Q(1000.)6055.6545
 Q(500.0)1984.0812
 Q(300.0)983.2868
 Q(225.0)694.1017
 Q(150.0)444.6887
 Q(75.00)220.0195
 Q(37.50)110.1397
 Q(18.75)55.2314
 Q(9.375)27.7827
detected in ISM/CSMyes (v = 0)


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder