cis-HOSO+
Oxyhydroxysulfonium, protonated SO2, cis isomer
Species tag 065510
Version1*
Date of EntrySep. 2011
ContributorH. S. P. Müller

The cis isomer of HOSO+ is much lower in energy than the trans isomer. Moreover, the available experimental transition frequencies are limited to low J. Therefore, an entry has not yet been created for the trans isomer. The experimental data was taken from
(1) V. Lattanzi, P. Thaddeus, M. C. McCarthy, and S. Thorwirth, 2010, J. Chem. Phys. 133, Art. No. 194305;
and from
(2) V. Lattanzi, C. A. Gottlieb, P. Thaddeus, S. Thorwirth, and M. C. McCarthy, 2011, Astron. Astrophys. 533, Art. No. L11.
The parameters released and the uncertainties used in the final fit differ slightly from those given in (1) and (2). Since the experimental data are restricted to Ka = 0 and 1, predictions with Ka ≥ 2 should be viewed with increasing caution, in particular b-type transitions. Moreover, predictions for transitions with Ka ≤ 1 should be reliable as long as the uncertainties do not exceed 200 kHz.
The dipole moment is from an ab initio calculation in (1).

Lines Listed4618
Frequency / GHz< 1000
Max. J61
log STR0-8.3
log STR1-5.3
Isotope Corr.-0.0
Egy / cm–10.0
 µa / D1.74
 µb / D0.49
 µc / D 
 A / MHz44183.5
 B / MHz9899.77
 C / MHz8070.10
 Q(300.0)14791.1607
 Q(225.0)9601.8563
 Q(150.0)5224.4628
 Q(75.00)1847.4420
 Q(37.50)654.0718
 Q(18.75)232.0102
 Q(9.375)82.5922
 Q(5.000)32.5634
 Q(2.725)13.3942
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder