KSH
Potassium hydrosulfide, X 1A'
Species tag 072506
Version1*
Date of EntryJuly 2018
ContributorH. S. P. Müller

Experimental results were reported by
(1) M. P. Bucchino, P. M. Sheridan, J. P. Young, M. K. L. Binns, D. W. Ewing, and L. M. Ziurys, 2013, J. Chem. Phys. 139, Art. No. 214307.
The 39K hyperfine split a-type transition frequencies from that work were also included in the fit. 39K HFS splitting may be resolvable at low values of J and higher values of Ka, but these transitions are deemed to be too weak even if the molecule will have been observed in space. The entry may be sufficiently accurate for all observational purposes. Transitions with predicted uncertainties exceeding 0.2 MHz should be viewed with some caution.
The dipole moment was taken from an ab initio calculation by
(2) H. S. P. Müller, 2018, unpublished.
Even though the molecule posseses a moderately large b-dipole moment component, no such transitions were calculated because their frequencies are too uncertain.

Lines Listed1936
Frequency / GHz< 803
Max. J115
log STR0-5.0
log STR1-3.5
Isotope Corr.-0.0524
Egy / cm–10.0
 µa / D11.1
 µb / D(0.40)
 µc / D 
 A / MHz298300.
 B / MHz3584.736
 C / MHz3535.010
 Q(500.0)30970.2335
 Q(300.0)14336.2627
 Q(225.0)9298.3087
 Q(150.0)5054.4263
 Q(75.00)1785.0044
 Q(37.50)631.0953
 Q(18.75)223.3799
 Q(9.375)79.4480
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder