The molecule is the slightly higher lying enol form
of methylglyoxal. The latter is also known as acetylformaldehyde
and pyruvaldehyde. The molecule was studied in the regions
128 to 166 and 285 to 329 GHz by
(1) J. Koucký, L. Kolesniková, K. Luková,
K. Vávra, P. Kania, A. Coutens, J.-C. Loison, J. K.
Jørgensen, A. Belloche, and Š. Urban,
2022, Astron. Astrophys. 666, Art. No. A158.
Also included were very accurate microwave data
from
(2) F. J. Lovas, R. D. Suenram, D. F. Plusquellic,
and H. Møllendal,
2003, J. Mol. Spectrosc. 222, 263.
The uncertainties from (2) were slightly conservative
in (2) and even more so in (1); implicitely assumed
uncertainties were used for the data from (1). Use of the
S reduction required two distortion parameters less
in the fit which is usually beneficial for the
calculated frequencies. Moreover, the S reduction is more
versatile and yields frequently better fits. The calculations
should be sufficient for all observational purposes.
Transition frequencies with calculated uncertainties
larger than 200 kHz should be viewed with caution.
The experimental dipole moment components were determined in (2).
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