CaSH
Calcium monohydrosulfide, X 2A'
Species tag 073504
Version1*
Date of EntryJuly 2018
ContributorH. S. P. Müller

Experimental results were published by
(1) A. Taleb-Bendiab, F. Scappini, T. Amano, and J. K. G. Watson, 1996, J. Chem. Phys. 104, 7431.
The entry may be sufficiently accurate for all observational purposes. Transitions with predicted uncertainties exceeding 0.2 MHz should be viewed with some caution.
The a-dipole moment component was published by
(2) C. T. Scurlock, T. Henderson, S. Bosely, K. Y. Jung, and T. C. Steimle, 1994, J. Chem. Phys. 100, 5481.
Even though the molecule posseses a moderately large b-dipole moment component, no such transitions were calculated because their frequencies are too uncertain. The value is from an ab initio calculation in (1).

Lines Listed3082
Frequency / GHz< 819
Max. J98
log STR0-6.0
log STR1-5.0
Isotope Corr.-0.0356
Egy / cm–10.0
 µa / D5.36
 µb / D(0.62)
 µc / D 
 A / MHz290607.
 B / MHz4253.69
 C / MHz4184.95
 Q(500.0)52815.3793
 Q(300.0)24474.2853
 Q(225.0)15879.6701
 Q(150.0)8635.2894
 Q(75.00)3050.9421
 Q(37.50)1079.0245
 Q(18.75)382.0692
 Q(9.375)135.9041
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder