CaCl
Calcium monochloride, X 2Σ+
Species tag 075502
Version1
Date of EntrySep. 2001
ContributorH. S. P. Müller

The experimental data was taken from
(1) K. Möller, H.-K. Schütze-Pahlmann, J. Hoeft, and T. Törring, 1982, Chem. Phys. 68, 399; and from
(2) W. E. Ernst and T. Törring, 1983, Phys Rev. A 27, 875. Spin-rotation transitions (ΔN = 0) from
(3) W. J. Childs, D. R. Cok, and L. S. Goodmann, 1982, J. Chem. Phys. 76, 3993
were also used in the fit, but they have not been merged because of their weakness.
For transitions with N = 4 – 3 or higher, the hyperfine splitting is smaller than ca. 1 MHz for the strong hfs components. Therefore, predictions without hyperfine structure are also available.
The dipole moment is from
(4) W. E. Ernst, S. Kindt, K. P. R. Nair, and T. Törring, 1984, Phys Rev. A 29, 1158.

Lines Listed1131
Frequency / GHz< 855
Max. J95
log STR0-7.3
log STR1-5.0
Isotope Corr.-0.1340
Egy / cm-10.0
 µa / D4.257
 µb / D 
 µc / D 
 A / MHz 
 B / MHz4551.780
 C / MHz 
 Q(300.0)11009.6099
 Q(225.0)8253.9895
 Q(150.0)5500.9569
 Q(75.00)2750.5031
 Q(37.50)1376.2410
 Q(18.75)689.3526
 Q(9.375)345.9730
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder