The data from a laboratory study and from astronomical
observations were summarized in
(1) R. Fuentetaja, C. Cabezas, Y. Endo, M. Agúndez,
B. Tercero, N. Marcelino, P. de Vicente, and J. Cernicharo,
2024, Astron. Astrophys. 688, Art. No. L29.
The 14N quadrupole coupling parameter was taken
from HNC3
(2) Y. Hirahara, Y. Ohshima, Y. Endo,
1993, Astrophys. J. 403, L83.
The calculations should be accurate enough for all observations.
Transition frequencies with calculated uncertainties
larger than 0.1 MHz should be viewed with caution.
14N hyperfine splitting may matter
in astronomical observations. Therefore, a
separate hyperfine calculation is provided for
J' ≤ 10 below 28 GHz.
NOTE: The partition function
does take into account the spin multiplicity
of the 14N nucleus !
The dipole moment is from a quantum chemical calculation
in (1).
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