TiS
Titanium monosulfide, X 3Δr, 48Ti main isotopolog
Species tag 080505
Version1*
Date of EntryNov. 2010
ContributorH. S. P. Müller

Transition frequencies for 48TiS, v = 0 and 1 and for 46TiS, v = 0 have been reported by
(1) R. L. Pulliam, L. N. Zack, and L. M. Ziurys, 2010, J. Mol. Spectrosc. 264, 50.
The data have been subjected to a combined fit. Some parameters were kept fixed to values from
(2) J. Jonsson and O. Launila, 1993, Mol. Phys. 79, 95. The predictions should be quite good throughout, but some caution is advised for extrapolations to low frequencies and to frequencies higher than 800 GHz.
The partition function values contain vibrational contributions. Ground state values are given in parentheses for temperatures with non-zero vibrational contributions.
The dipole moment was determined in
(3) R. R. Bosquet, K.-I. Namiki, and T. C. Steimle, 2000, J. Chem. Phys. 113, 1566.

Lines Listed261
Frequency / GHz< 1102
Max. J91
log STR0-4.5
log STR1-4.0
Isotope Corr.-0.155
Egy / cm–10.0
 µa / D5.75
 µb / D 
 µc / D 
 A / MHz 
 B / MHz6060.14
 C / MHz 
 Q(500.0)10160.4647 (8109.9901)
 Q(300.0)4561.4712 (4246.0905)
 Q(225.0)2970.1581 (2886.1051)
 Q(150.0)1646.7485 (1638.9359)
 Q(75.00)624.2321 (624.2181)
 Q(37.50)269.6015
 Q(18.75)132.2886
 Q(9.375)67.4516
 Q(5.000)37.2797
 Q(2.725)21.6428
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder