2,5-c-C6H6S
2,5-Cyclohexadienthione
Species tag 110501
Version1*
Date of EntryApr. 2026
ContributorH. S. P. Müller

The microwave transition frequencies were reported by
(1) M. Araki, M. Sanz-Novo, C. P. Endres, P. Caselli, V. M. Rivilla, I. Jiménez-Serra, L. Colzi, S. Zeng, A. Megías, Á López-Gallifa, A. Martínez-Henares, D. San Andrés, S. Martín, M. A. Requena-Torres, J. G. de la Concepción, and V. Lattanzi, 2026, Nat. Astron. 10, 401.
The entry was truncated at J = 55 and 150 GHz because of the limited line list. Transitions with uncertianties exceeding 0.1 MHz should be viewed with great caution. Transitions with ΔKa = 2 should be viewed with additional caution.
At low temperatures, it may be necessary to discern between ortho-2,5-c-C6H6S and para-2,5-c-C6H6S. The ortho and para states are described by Ka odd and even, respectively. The nuclear spin-weights are 9 and 7 for ortho-2,5-c-C6H6S and para-2,5-c-C6H6S, respectively. The JKaKc = 111 level is the lowest ortho level. It is 0.2178 cm–1 above ground.
The dipole moment is from a quantum chemical calculation in (1).

Lines Listed3387
Frequency / GHz< 150
Max. J55
log STR0-10.5
log STR1-5.0
Isotope Corr. 
Egy / (cm–1)0.0
 µa / D4.73
 µb / D 
 µc / D 
 A / MHz5285.46
 B / MHz1608.452
 C / MHz1242.731
 Q(300.0)2157584.0245
 Q(225.0)1401191.4375
 Q(150.0)762619.8103
 Q(75.00)269618.0750
 Q(37.50)95341.7998
 Q(18.75)33724.9108
 Q(9.375)11935.9738
 Q(5.000)4657.5698
 Q(2.725)1880.1801
detected in ISM/CSMyes


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schlöder