===== Detection of Magnesium Polyacetylide Cations toward CW Leonis =====
J. Cernicharo, C. Cabezas, J. R. Pardo, M. Agúndez, O. Roncero, B. Tercero, N. Marcelino, M. Guélin, Y. Endo, and P. de Vicente\\
reported on the\\
**[[https://doi.org/10.1051/0004-6361/202346467|The Magnesium Paradigm in IRC +10216: Discovery of MgC4H+, MgC3N+, MgC6H+, and MgC5N+]]**\\
//Astron. Astrophys.// **672**, Art. No. L13 (2023).\\
The molecules were identified in the course of a molecular line survey with the 40 m Yebes radio telescope between 31.0 and 50.3 GHz.
All identifications relied on quantum chemical calculations in the absense of Laboratory spectroscopic data.
Seven successive, unblended transitions with 11 ≤ //J"// ≤ 17 were identified for MgC4H+. In addition, nine successive transitions with 25 ≤ //J"// ≤ 33 were identified between 72.4 and 95.6 GHz in data of an IRAM 30 m molecular line survey; two transitions were partly blended.
16 transitions with 26 ≤ //J"// ≤ 41 were accessed in the case of MgC6H+. Four transitions were partly blended, one was blended heavily.
Seven successive transitions with 11 ≤ //J"// ≤ 17 were identified for MgC3N+ of which five were partially blended.
16 transitions with 27 ≤ //J"// ≤ 42 were accessed in the case of MgC5N+. Nine were partially blended, one heavily, and two lines were too week to be detected securely.
The rotational temperatures are around 20 K; the value of ~10 K for MgC3N+ should probably be viewed with great caution. The abundance ratios are about 48 : 12 : 25 : 11 for MgC4H+, MgC3N+. MgC6H+, and MgC5N+, respectively. The cations are about a factor of 200 less abundant than their neutral counterparts in the case of MgC4H+ and MgC6H+, whereas is is about a factor of 100 for MgC3N+ and about a factor of 50 for MgC5N+. Again, the ratios for MgC3N+ should be viewed with caution.\\
\\
----
Contributor(s): H. S. P. Müller; 05, 2023
----