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--- molecules:ism:cyanopyren [2024/11/21 14:28] – mueller
+++ molecules:ism:cyanopyren [2025/02/24 16:11] (current) – mueller
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-===== On the Detection of Cyanoacenaphtalenes, C<sub>16</sub>H<sub>9</sub>CN, in the ISM =====
+===== On the Detection of Cyanopyrenes, C<sub>16</sub>H<sub>9</sub>CN, in the ISM =====
+G. Wenzel, I. R. Cooke, P. B. Changala, E. A. Bergin, S. Zhang, A. M. Burkhardt, A. N. Byrne, S. B. Charnley, M. A. Cordiner, M. Duffy, Z. T. P. Fried, H. Gupta, M. S. Holdren, A. Lipnicky, R. A. Loomis, H. T. Shay, C. N. Shingledecker, M. A. Siebert, D. A. Stewart, R. H. J. Willis, C. Xue, A. J. Remijan, A. E. Wendlandt, M. C. McCarthy, and B. A. McGuire\\
+reported on the\\
+**[[https://doi.org/10.1126/science.adq6391|Detection of Interstellar 1-Cyanopyrene: A Four-ring Polycyclic Aromatic Hydrocarbon]]**\\
+//Science// **386**, 810−813 (2024).\\
+The molecule was identified in the course of the GOTHAM survey of TMC-1 casrried out with the 100 m GBT dish. Several oblate paired //a//-type rotational transitions with 31 ≤ //J// ≤ 37 and //K<sub>c</sub>// close to //J//. Each pair of lines is close to the noise limit, but stacking achieves a S/N of about 7. The derived column density is, for example, about twice that of each of 1- and 2-cyanonaphtalene and only slightly less than that of benzonitrile.\\
+The CfA issued a **[[https://www.cfa.harvard.edu/news/astronomers-discover-new-building-blocks-complex-organic-matter|press release]]**.\\
+\\
+G. Wenzel, T. H. Speak, P. B. Changala, R. H. J. Willis, A. M. Burkhardt, S. Zhang, E. A. Bergin, A. N. Byrne, S. B. Charnley, Z. T. P. Fried, H. Gupta, E. Herbst, M. S. Holdren, A. Lipnicky, R. A. Loomis, C. N. Shingledecker, C. Xue, A. J. Remijan, A. E. Wendlandt, M. C. McCarthy, I. R. Cooke, and B. A. McGuire\\
+announced the\\
+**[[https://doi.org/10.1038/s41550-024-02410-9|Detections of Interstellar Aromatic Nitriles 2-Cyanopyrene and 4-Cyanopyrene in TMC-1]]**\\
+//Nat. Atron.// **9**, 262−270 (2025).\\
+The isomers of 1-cyanopyrene were detected in a manner very similar to this one. The derived column densities of 1-cyanopyrene : 2-cyanopyrene  : 4-cyanopyrene are compatible with the 4 : 2 : 4 ratios of the number of equivalent substitution positions in pyrene.\\
+\\
+----
+Contributor(s): H. S. P. Müller; 11, 2024; 02, 2025
+----
-G. Wenzel, I. R. Cooke, P. B. Changala, Edwin A. Bergin Shuo Zhang Andrew M. Burkhardt Alex N. Byrne Steven B. Charnley Martin A. Cordiner Miya Duffy Zachary T. P. Fried Harshal Gupta Martin S. Holdren Andrew Lipnicky Ryan A. Loomis Hannah Toru Shay Christopher N. Shingledecker Mark A. Siebert D. Archie Stewart Reace H. J. Willis Ci Xue Anthony J. Remijan Alison E. Wendlandt Michael C. McCarthy Brett A. McGuire