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molecules:ism:hc2chs [2021/06/30 16:47] – mueller | molecules:ism:hc2chs [2021/06/30 16:57] (current) – mueller |
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**[[https://doi.org/10.1051/0004-6361/202141297|The Sulphur Saga in TMC-1: Discovery of HCSCN and HCSCCH]]**\\ | **[[https://doi.org/10.1051/0004-6361/202141297|The Sulphur Saga in TMC-1: Discovery of HCSCN and HCSCCH]]**\\ |
//Astron. Astrophys.// **650**, Art. No. L14 (2021).\\ | //Astron. Astrophys.// **650**, Art. No. L14 (2021).\\ |
HC<sub>2</sub>CHS was identified through 7 //a//-type transitions with 5 ≤ //J// ≤ 8 and //K<sub>a</sub>// ≤ 2 in the course of a molecular line survey of the prototypical cold dark molecular cloud TMC-1 carried out with the Yebes 40 m radio telescope between 32.8 and 49.2 GHz. A value of //T//<sub>rot</sub> = 5.0 K was assumed, in keeping with cyanothioformaldehyde. The column density of HC<sub>2</sub>CHS is about a factor of 5 lower than that of the isovalent HC<sub>2</sub>CHO, similar to the corresponding factor of 10 between thioformaldehyde and formaldehyde. In addition, the column density of HC<sub>2</sub>CHS is about a factor of 4 lower than that of the isoelectronic HC(S)CN; the latter molecule is unusually abundant in TMC-1.\\ | HC<sub>2</sub>CHS was identified through 6 //a//-type transitions, of which 5 appear to be unblended, with 5 ≤ //J// ≤ 8 and //K<sub>a</sub>// ≤ 1 in the course of a molecular line survey of the prototypical cold dark molecular cloud TMC-1 carried out with the Yebes 40 m radio telescope between 30.1 and 50.4 GHz. A value of //T//<sub>rot</sub> = 5.0 K was assumed, in keeping with cyanothioformaldehyde. The column density of HC<sub>2</sub>CHS is about a factor of 5 lower than that of the isovalent HC<sub>2</sub>CHO, similar to the corresponding factor of 10 between thioformaldehyde and formaldehyde. In addition, the column density of HC<sub>2</sub>CHS is about a factor of 4 lower than that of the isoelectronic HC(S)CN; the latter molecule is unusually abundant in TMC-1.\\ |
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